| Ultimate Spider-Man vs The Sinister Six | Graduation Day - Part 2: Superhero animation. Peter must stop Doc Oc and the Superior Sinister Six from taking over the world. [S] S4 Ep26 | Sat, Mar 2, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | Graduation Day - Part 1: Superhero animation. Doc Oc threatens to bring harm on everything Peter cares about if he ever puts on his mask again. [S] S4 Ep25 | Sat, Feb 23, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 3: Action-packed superhero animation. The Web Warriors and the Spider Slayers join forces to flush out the secret villain. [S] S4 Ep24 | Sat, Feb 16, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 2: Action-packed superhero animation. Spider-Man, Doc Oc, and Scarlet Spider all search for clues to Scarlet's past. [S] S4 Ep23 | Sat, Feb 9, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 1: Superhero animation. Spider-Man discovers a sinister new plot when he is attacked by an artificial version of himself. [S] S4 Ep9 | Sat, Feb 2, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 4: Superhero animation. Back in Kid Arachnid's universe, the adventurers bump into Spider-Gwen on their quest. [S] S4 Ep21 | Sat, Jan 26, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 3: Superhero animation. Spider-Man and Kid Arachnid search the Noir Timeline for more pieces of the Siege Perilous. [S] S4 Ep20 | Sat, Jan 19, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 2: Superhero animation. Spider-Man and Kid Arachnid end up in the Wild West looking for pieces of the Siege Perilous. [S] S4 Ep19 | Sat, Jan 12, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 1: Superhero animation. Spider-Man and Kid Arachnid head to other dimensions looking for the Siege Perilous. [S] S4 Ep18 | Sun, Jan 6, 8:30 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 3: Animated adventures with the friendly neighbourhood Spider-Man! The Carnage symbiote makes one final play for destruction. [S] S4 Ep4 | Sat, Jan 5, 8:30 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 2: Spider-Man assembles his super hero friends to help halt the spreading chaos! [S] S4 Ep16 | Sun, Dec 30, 8:25 am | CITV | 30 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 1: Animated adventures with the friendly neighbourhood Spider-Man! Spidey and Agent venom go on the hunt for stolen Venom samples. [S] S4 Ep2 | Sat, Dec 29, 8:25 am | CITV | 30 mins |
| Ultimate Spider-Man vs The Sinister Six | The Moon Night Before Christmas: Animated adventures with the friendly neighbourhood Spider-Man! Peter must confront his own ghost of Christmas past... [S] S4 Ep1 | Wed, Dec 26, 8:30 am | CITV | 35 mins |
| Ultimate Spider-Man vs The Sinister Six | The Moon Night Before Christmas: Animated adventures with the friendly neighbourhood Spider-Man! Peter must confront his own ghost of Christmas past... [S] S4 Ep1 | Sun, Dec 23, 8:30 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | Graduation Day - Part 1: Superhero animation. Doc Oc threatens to bring harm on everything Peter cares about if he ever puts on his mask again. [S] S4 Ep25 | Tue, Oct 16, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 3: Action-packed superhero animation. The Web Warriors and the Spider Slayers join forces to flush out the secret villain. [S] S4 Ep24 | Mon, Oct 15, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 2: Action-packed superhero animation. Spider-Man, Doc Oc, and Scarlet Spider all search for clues to Scarlet's past. [S] Ep10 | Fri, Oct 12, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Spider Slayers - Part 1: Superhero animation. Spider-Man discovers a sinister new plot when he is attacked by an artificial version of himself. [S] Ep9 | Thu, Oct 11, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 4: Superhero animation. Back in Kid Arachnid's universe, the adventurers bump into Spider-Gwen on their quest. [S] Ep8 | Wed, Oct 10, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 3: Superhero animation. Spider-Man and Kid Arachnid search the Noir Timeline for more pieces of the Siege Perilous. [S] Ep7 | Tue, Oct 9, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 2: Superhero animation. Spider-Man and Kid Arachnid end up in the Wild West looking for pieces of the Siege Perilous. [S] Ep6 | Mon, Oct 8, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Return to the Spider-Verse - Part 1: Superhero animation. Spider-Man and Kid Arachnid head to other dimensions looking for the Siege Perilous. [S] Ep5 | Fri, Oct 5, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 3: Animated adventures with the friendly neighbourhood Spider-Man! The Carnage symbiote makes one final play for destruction. [S] Ep4 | Thu, Oct 4, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 2: Spider-Man assembles his super hero friends to help halt the spreading chaos! [S] Ep3 | Wed, Oct 3, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Symbiote Saga Part 1: Animated adventures with the friendly neighbourhood Spider-Man! Spidey and Agent venom go on the hunt for stolen Venom samples. [S] Ep2 | Tue, Oct 2, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The Moon Night Before Christmas: Animated adventures with the friendly neighbourhood Spider-Man! Peter must confront his own ghost of Christmas past... [S] Ep1 | Mon, Oct 1, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | A Strange Little Halloween: When trick-or-treaters start turning into monsters, Spider-Man, Doctor Strange and Ant-Man team up to stop it. [S,AD] S4 Ep13 | Fri, Sept 28, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Agent Web: Animated adventures. When a battered Nova asks for help finding Nick Fury, Spider-Man tracks him to the dangerous ruins of an ancient city. [S,AD] S4 Ep12 | Thu, Sept 27, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 2: When Doc Ock learns the key to Hydra Island is at Aunt May's house, Spider-Man must protect her. [S,AD] S4 Ep11 | Wed, Sept 26, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 1: Spider-Man faces the culmination of all of Doc Ock's evil plans when the new Sinister Six attacks the Web Warriors. [S,AD] S4 Ep10 | Tue, Sept 25, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Force of Nature: After receiving a mysterious signal from an unknown base, Spider-Man traces it to an abandoned building in the hope of finding Nick Fury. [S,AD] S4 Ep9 | Mon, Sept 24, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Anti-Venom: Web-slinging animated adventures. Doc Ock and his new assistant Michael Morbius create Anti-Venom in order to destroy one of the Web Warriors. [S,AD] S4 Ep8 | Fri, Sept 21, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Beached: As Spider-Man pursues Vulture, his pursuit brings him to a nearby island where he discovers that Doc Ock has captured Sandman and is trying to clone him. [S,AD] S4 Ep7 | Thu, Sept 20, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Double Agent Venom: Spider-Man and Scarlet Spider must overcome Kraven in order to rescue kidnapped teammate Agent Venom. [S,AD] S4 Ep6 | Wed, Sept 19, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Lizards: Dr Curt Connors returns as Lizard and now has a bite that turns anyone bitten into Lizards. Spider-Man must work fast to save everyone. [S,AD] S4 Ep5 | Tue, Sept 18, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Iron Vulture: Peter and Miles stumble upon a plot by Doctor Octopus to raid Oscorp in order to access the computers so that Vulture can learn more about his past. [S,AD] S4 Ep4 | Mon, Sept 17, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Miles from Home: Doc Ock manages to convince Green Goblin to ally with him and the Sinister Six, while Miles is welcomed to the Web Warriors by Peter. [S,AD] S4 Ep3 | Fri, Sept 14, 7:49 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | A Strange Little Halloween: When trick-or-treaters start turning into monsters, Spider-Man, Doctor Strange and Ant-Man team up to stop Baron Mordo's evil plot. [S,AD] | Sat, Feb 10, 7:05 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | A Strange Little Halloween: When trick-or-treaters start turning into monsters, Spider-Man, Doctor Strange and Ant-Man team up to stop Baron Mordo's evil plot. [S,AD] | Tue, Feb 6, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Agent Web: Animated adventures. When a battered Nova asks for help finding Nick Fury, Spider-Man tracks him to the dangerous ruins of an ancient city. [S,AD] | Mon, Feb 5, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Agent Web: Animated adventures. When a battered Nova asks for help finding Nick Fury, Spider-Man tracks him to the dangerous ruins of an ancient city. [S,AD] | Sun, Feb 4, 7:05 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 2: When Doc Ock learns that the key to a device that will retrieve Hydra Island is at Aunt May's house, Spider-Man must protect her. [S,AD] | Sat, Feb 3, 7:05 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 2: When Doc Ock learns that the key to a device that will retrieve Hydra Island is at Aunt May's house, Spider-Man must protect her. [S,AD] | Fri, Feb 2, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 1: Spider-Man faces the culmination of all of Doc Ock's evil plans when the new Sinister Six attacks the Web Warriors. [S,AD] | Thu, Feb 1, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Force of Nature: After receiving a mysterious signal from an unknown base, Spider-Man traces it to an abandoned building in the hope of finding Nick Fury. [S,AD] | Wed, Jan 31, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Anti-Venom: Web-slinging animated adventures. Doc Ock and his new assistant Michael Morbius create Anti-Venom in order to destroy one of the Web Warriors. [S,AD] | Tue, Jan 30, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | The New Sinister Six - Part 1: Spider-Man faces the culmination of all of Doc Ock's evil plans when the new Sinister Six attacks the Web Warriors. [S,AD] | Sun, Jan 28, 7:05 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | Force of Nature: After receiving a mysterious signal from an unknown base, Spider-Man traces it to an abandoned building in the hope of finding Nick Fury. [S,AD] | Sat, Jan 27, 7:05 am | CITV | 25 mins |
| Ultimate Spider-Man vs The Sinister Six | Double Agent Venom: Spider-Man and Scarlet Spider must overcome Kraven in order to rescue kidnapped teammate Agent Venom. [S,AD] | Fri, Jan 26, 7:50 am | CITV | 31 mins |
| Ultimate Spider-Man vs The Sinister Six | Lizards: Dr Curt Connors returns as Lizard and now has a bite that turns anyone bitten into Lizards. Spider-Man must work fast to save everyone. [S,AD] | Thu, Jan 25, 7:50 am | CITV | 31 mins |